Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ2 N,O}zinc

نویسندگان

  • Dingjun Zhang
  • Hong Yu
  • Yue-Bao Jin
  • Ke-Wei Lei
چکیده

In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within normal ranges. The dihedral angle between the least-squares planes of the aromatic rings within each ligand is 82.76 (17)°.

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منابع مشابه

Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ2 N,O}cobalt(II)

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Redetermination of bis­(2-formyl­phenolato-κ2 O,O′)nickel(II) as bis­[2-(imino­meth­yl)phenolato-κ2 N,O′]nickel(II)

The crystal structure of bis-(2-formyl-phenolato-κ(2)O,O')nickel(II), [Ni(C(7)H(5)O(2))(2)], a square-planar centrosymmetric complex, has been reported previously [Li & Chen (2006). Acta Cryst. E62, m1038-m1039]. However, a number of warning signs allows the assumption that the carbonyl group in the salicylaldehydate ligand of the claimed complex is incorrect. The crystal structure was therefor...

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012